Ilya Prigogine's Advances in Chemical Physics, Volume 19 PDF

By Ilya Prigogine

ISBN-10: 0470143673

ISBN-13: 9780470143674

ISBN-10: 0471699241

ISBN-13: 9780471699248

The Advances in Chemical Physics sequence presents the chemical physics and actual chemistry fields with a discussion board for serious, authoritative reviews of advances in each sector of the self-discipline. jam-packed with state of the art examine suggested in a cohesive demeanour now not came across somewhere else within the literature, every one quantity of the Advances in Chemical Physics sequence serves because the excellent complement to any complicated graduate category dedicated to the research of chemical physics.


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Extra resources for Advances in Chemical Physics, Volume 19

Sample text

Franklin and Field found dependence on E-’. They suggested that, although their cross sections were of the order of magnitude predicted by the G-S theory, it was not a complete explanation and the finer details of the rates were determined by other unknown factors. Hamill and his coworkers37 investigated systems which varied in complexity from those of Stevenson and Schissler to those of Franklin, Field and Lampe. They found many reactions whose cross section showed an E-’ rather than an E-”’ dependence.

C. Rankin and J. Light, J . Chem. Phys. 51, 1701 (1969). 34. S. Chan, J. Light, and J. Lin, J. Chem. r. 49, 86 (1968). 35. R. Gordon, J. Chem. Phys. 51, 14 (1969). 36. P. Pechukas and J. Light, J. Chem. Phys. 44, 3897 (1966). 37. R . E. Wyatt, J . Chem. Phys. 51, 3489 (1969). 38. R. N. Portcr and M. Karplus, J. Chem. Phys. 40, 1105 (1964). 39. G. Miller, private communication. 40. H. S. Johnston and D. Rapp, J . Am. Chem. Soc. 83, 1 (1961). 41. D. Russell, private communication. 42. D. Russell and J.

41342 The large difference between the appearance potentials of H: and He’ or Ne+ made identification of reactant ions simple. Investigations of appearance potentials of the product ions immediately showed that, contrary to expectation, reaction was proceeding in both cases through the “endothermic” channels. A peculiar energy dependence was observed for these reactions with some evidence of an energy barrier or threshold, and at higher ion kinetic energies, a rather rapid decrease in rate with increasing repeller voltage.

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Advances in Chemical Physics, Volume 19 by Ilya Prigogine

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